Tagged: trinidad

Recommended oil – Automotive

oil_car

What type of oil should I use in my car?

Always follow what the OEM recommends! A quick google search can help you find the required lubricant if you don’t have the owner’s manual.

Most modern vehicles use lighter weight oils compared to older vehicles. Let’s think about cars back in 1950. They were larger, with big engines. With a big engine, it would mean that the lines carrying the oil would be larger. Thus, a heavier oil (50 weight) would be the most appropriate.

Now, fast forward to cars today. The engines are smaller, (albeit with a lot more horsepower as well!). If the size of the engine has changed, then the size of the lines carrying the lubricant will change as well. These lines will get smaller. If the lines are smaller, then the liquid that has to flow through them, should be lighter (thinner).

We can use an analogy of a straw trying to pull up molasses.

With a large straw, we could pull up the molasses faster than with a thinner straw. This is similar to the older cars, they would have thicker “straws” (lines) that would have allowed them to adequately pump the lubricant.

In the newer cars, the straw has gotten thinner, so it can’t pull up the molasses anymore. If we tried to pull up water instead, it would definitely flow faster than the molasses and not have as much strain on the person pulling up the water (pump in the engine). Hence, lighter oils are used in modern cars.

Most recommendations can be found by contacting the OEM or even doing a bit of Google searching with the year of manufacture for the car and of course the model.

Additives and their properties

Properties of Additives in Lubricants

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Each lubricant has a varying percentage of additives as not all lubricants are created equally. Lubricants are designed based on their application or use within the industry. For instance, an engine oil is typically composed of 30% additives, 70% base oil while turbine oils comprise 1% additives and 99% base oil.

Therefore, particular attention must be paid to getting the additive compositions to be just right for the application and ensuring that the additives can perform their functions.

Each additive has a particular function and is used as per the application of the lubricant. We have adapted the following from Analysts Inc – Basic Oil Analysis which describes the purpose of some of the most commonly used additives in lubricants.

additives

ICML 55 – the revolution in the lubrication sector

icml_stds

What is ICML 55?

ICML 55 is revolutionizing the lubrication industry! It is so exciting to be around at this time when it has started its implementation. For those who aren’t aware of ICML 55, here are a couple of notes on it.

ICML 55 was born out of ISO 55000 which speaks to Asset Management. From this standard, 3 standards were developed to guide the lubrication industry since no previous standards existed within the lubrication industry.

  • ICML 55.1 - Requirements for the Optimized Lubrication of Mechanical Physical Assets
  • ICML 55.2 - Guideline for the Optimized Lubrication of Mechanical Physical Assets
  • ICML 55.3 - Auditors' Standard Practice and Policies Manual

ICML 55.1 has already been completed, while 55.2 should be done at the end of this year and 55.3 scheduled for 2020.

These are exciting times!

Here’s the official press release:

https://info.lubecouncil.org/2019/04/04/icml-introduces-icml-55-asset-management-standards-mle-engineer-certification/

While ICML 55.1 was only launched in April of this year (2019), it is a standard that the lubrication industry has been in need of for several years. It addresses the “Requirements for the Optimized Lubrication of Mechanical Physical Assets”.

What exactly are the assets covered? Here they are:

  • Rotating & Reciprocating Machines, Powertrains, Hydraulic Systems and lubricated subcomponents
  • Assets with lubricants that reduce friction, wear, corrosion, heat generation or facilitate transfer of energy
  • Finished products from API categories I-V
  • Non Machinery support assets (Personnel, policies, procedures, storage facilities and management)
icml_55

There are also fluids and assets which are NOT covered:

  • Fuels, coolants, metal-working fluids, pastes, fogging agents, preservative fluids, coating materials, heat-transfer fluids, brake fluids, cosmetic lubricants
  • Solid lubricants (e.g., powders and surface treatments used as coating rather than to reduce friction between surfaces in motion)
  • Additives independent of the finished lubricant
  • Electrical transformer oils and anti-seize compounds
  • Fluids and materials derived from a petroleum or petroleum-like base
  • Fluids that do not serve a lubrication function
Photo Credit: https://info.lubecouncil.org/icml-55-standards/
Photo Credit: https://info.lubecouncil.org/icml-55-standards/

ICML 55.1 speaks to the “Requirements for the Optimized Lubrication of Mechanical Physical Assets” it also describes and defines 12 interrelated areas that can be incorporated in a lubrication program. This has never been officially documented before, nor has any standard been published as a guideline for lubrication programs.

The 12 areas are outlined below:

  1. SKILLS: Job Task, Training, and Competency
  2. MACHINE: Machine Lubrication and Condition Monitoring Readiness
  3. LUBRICANT: Lubricant System Design and Selection
  4. LUBRICATION: Planned and Corrective Maintenance Tasks
  5. TOOLS: Lubrication Support Facilities and Tools
  6. INSPECTION: Machine and Lubricant Inspection
  7. LUBRICANT ANALYSIS: Condition Monitoring and Lubrication Analysis
  8. TROUBLESHOOT: Fault/Failure Troubleshooting and RCA
  9. WASTE: Lubricant Waste Handling and Management
  10. ENERGY: Energy Conservation and Environmental Impact
  11. RECLAIM: Oil Reclamation and System Decontamination
  12. MANAGEMENT: Program Management and Metrics

As per ICML's website, here's a list of people that the new standard can benefit:

Photo Credit: https://info.lubecouncil.org/icml-55-standards/

 

Check out the ICML 55 standards today and apply it to your organization!

Used Oil Analysis Tips

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“When should an oil sample really be taken?”

In used oil analysis, oil samples can be taken at any time, but one should always consider the insight that they are trying to gain before testing the sample. This is crucial in deciding the type of tests and the intervals at which they should be performed.

 

For instance, if we are testing the quality of the oil or we want to compare a fresh batch to a used one, then we can take a sample directly from the drum.

If we are trying to decide the rate at which the additives are being depleted or wear being accumulated then we can take a sample at different operating hours to trend the data. This method can work if we are trying to determine the most appropriate run time for a lubricant in particular conditions.

However, if we are trying to track the health of the components on a regular basis as part of our PM program then taking a sample at the end of the scheduled maintenance interval is desired.

Taking an oil sample from a component is like performing a blood test by the doctor. It helps us to understand what’s really happening. It can show us if there is excessive wear, contamination or lubricant degradation which allows us to identify its “health”. However, the correct tests need to be carried out to determine these conditions.

There must be a reason behind taking the oil sample, not just a random act. When trying to establish a trend regarding a particular aspect of the oil, this should guide your choice of tests otherwise we can end up paying for tests that do not add value.

Always ensure sound reasoning behind testing rather than just checking the box!

While taking an oil sample at the end of the scheduled operating hours is very convenient, is it truly efficient?

When a piece of equipment is scheduled for maintenance, it is usually taken out of service for a couple of hours to perform the assigned
maintenance tasks.

However, if an oil sample is taken a couple days in advance of the scheduled maintenance, then when the results return the maintenance team can be on the lookout for issues highlighted by the results.

For instance, if the value for iron was significant or rising then they can perform inspections for areas which may cause this type of wear and address this challenge while the equipment is offline.

The graphic on the side can be used as a quick guide to determining when to take a sample.

Remember to always evaluate the reason behind establishing the sampling frequency before scheduling sampling.

sampling_freq

Lubricant Deterioration Identifications

What the difference between Shelf Life and Service Life?

There’s a major difference between Shelf life and Service life especially when it concerns lubricants!

No one wants to put expired lubricants into their equipment! This can cause unexpected failures which can lead to unplanned downtime which can continue to spiral down the costly path of unproductivity!

shelf_life_service_life

Shelf Life

The Shelf life is usually what is stamped by the Manufacturer indicating the length of time the product can remain in its current packaging before being deemed unsuitable for use. These can typically be found on the packaging.

Service Life

The Service life however is determined by the application and conditions under which the lubricant is being used. Usually, estimated running hours / mileage are given by the equipment manufacturer in the maintenance section of the manual. (Condition monitoring can also be used to determine appropriate service intervals.)

However, how will someone know if the product has deteriorated while still in its original packaging?  What should someone typically look for?

Above are some tips for identification of deterioration in lubricants. Take a note of these for the next time you are unsure of the integrity of your lubricants.

Conditions that affect lubricants

What conditions affect lubricants?

How are your lubricants currently stored?

Are you storing lubricants under the correct conditions?

These questions have come up a dozen times during audits and countless warehouse meetings!

conditions
Conditions that affect lubricants

To answer these questions, there are five main conditions that can affect lubricants. We have detailed them along with the effects of these conditions on the lubricant.

  • Temperature – if incorrect can lead to oxidation. For every 10C rise in temperature above 40C the life of the lubricant is halved.
  • Light – too much can lead to oxidation especially for light sensitive lubricants such as transformer oils. Hence the reason that most packaging is opaque.
  • Water – this usually works with additives to cause their depletion or contamination of the product. Water in any lubricant is bad (especially for transformer oils as they are involved in the conduction of electricity.
  • Particulate contamination – contamination can occur by air borne particles if packaging is left open or if dirty containers/vessels are used to transfer the lubricant from its packaging to the component.
  • Atmospheric contamination – this affects viscosity and promotes oxidation and can occur if packaging is left open. For instance, if a drum is not properly resealed or capped after usage or the most common practice of leaving the drum open with the drum pump on the inside.

Different types of lubricant degradation

Why is it important to know the types of lubricant degradation?

It’s important since it helps us to figure out why or in some instance how, the lubricant degraded! Usually degradation is the change that occurs when the lubricant can no longer execute its five main functions:

  • the reduction of friction
  • minimization of wear
  • distribution of heat
  • removal of contaminants and
  • improvement of efficiency.

 

lubricant_fails
Types of lubricant Degradation Mechanisms

There are 6 main types of Lubricant Degradation as detailed below. Each type produces various by products which can enable us to understand the reason for the degradation and eliminate that / those reasons.

Here are the 6 main types of Lubricant Degradation:

1. Oxidation
2. Thermal Breakdown
3. Microdieseling
4. Additive Depletion
5. Electrostatic Spark Discharge
6. Contamination

As discussed, each mechanism produces distinct results which help us in their identification! Check out our article on why lubricants fail for more info!

Oxidation

oxidation

What is Oxidation?

One of the major types of oil degradation is Oxidation. But what is it exactly, as applied to a lubricant?

Oxidation is the addition of oxygen to the base oil of the lubricant to form either of the following:

  • Aldehydes
  • Ketones
  • Hydroperoxides
  • Carboxylic Acids

Wow… too many chemical names right?! These help to pinpoint the conditions responsible and then we can address them accordingly. Each of these by products are produced by different types of reactions or in some cases different stages of the oxidation process. It is key to note the type of by product as it gives us a clue to the root of the issue through which oxidation occurs.

For instance, the presence of Carboxylic acids can result in the formation of Primary Amides which can lead to heavy deposits. Early detection of the Carboxylic acids can help us prevent this. Once we determine the source of oxidation to produce the carboxylic acids, we can in turn remove this from the system.

 

Oxidation Stages

Oxidation does not happen in an instant. Usually, it follows a series of events which eventually lead to oxidation. Like any process in life, there are different stages for Oxidation:

  • Initiation – Production of the free radical via the lubricant and catalyst.
  • Propagation – Production of more free radicals via additional reactions
  • Termination – Continuation of oxidation process after the antioxidants have been depleted or the antioxidant stops the oxidation process.
Stages of Oxidation

Results of Oxidation

Why is Oxidation bad for the lubricant? What can it ultimately result in?

Well, oxidation can result in the formation or lead up to the following:

  • Varnish
  • Loss of antifoaming properties
  • Additive depletion
  • Base oil breakdown
  • Increase in viscosity
  • Sludge

None of these are good for the lubricant!!!!!!!!! If you see any of these signs be sure to test for oxidation and identify the root cause for the introduction of oxygen in your system.

tests for oxidation

Oxidation Tests

Now that we know more about oxidation… what tests can be performed to prevent it?

There are 6 main tests that can be performed:

  • RPVOT (Rotating Pressure Vessel Oxidation Test)
  • RULER (Remaining Useful Life Evaluation Routine)
  • MPC (Membrane Patch Calorimetry)
  • FTIR (Fourier Transform Infrared)
  • Colour (ASTM D1500)
  • Acid Number (ASTM D974)

One must be careful in selecting which test to apply, this is heavily dependent on the type of lubricant and its application.

For instance, if we perform the RULER test and the antioxidant levels have depleted significantly, we can suspect that oxidation is occurring or has stopped. Charting the rate of antioxidant depletion, can determine the rate of oxidation. This can assist us to forecast the time remaining before antioxidants have been depleted and can no longer protect the base oil.

Thermal Degradation vs Oxidation

What’s the difference between Thermal Degradation and Oxidation of a lubricant?

ox_vs_td

The two major differences are the contributory factors and the by products that are produced.

For oxidation, both oxygen and temperature are critical to the degradation of the lubricant however, in thermal degradation, the temperature of the lubricant exceeds its thermal stability (usually in excess of 200°C).

Oxidation usually occurs through the release of free radicals which deplete the antioxidants however, Thermal Degradation consists of polymerization of the lubricant.

Oxidation produces aldehydes, ketones, hydroperoxides, carboxylic acids varnish and sludge. On the other hand, Thermal Degradation produces coke as the final deposit.

Microdieseling

microdieseling

What is Microdieseling?

Microdieseling is also called Compressive Heating and is a form of pressure induced thermal degradation.

The oil goes through 4 stages in this degradation process:

1. There is a transition of entrained air from a low pressure to a high pressure zone

2. This produces localized temperatures in excess of 1000°C

3. The Bubble interface becomes carbonized

4. The oil darkens rapidly and produces carbon deposits due to oxidation

The conditions required for microdieseling can be either:

  • Low flashpoint with LOW implosion pressure
  • Low flashpoint with HIGH implosion pressure

For a low flashpoint with a HIGH implosion pressure, this constitutes to ignition products of incomplete combustion such as soots, tars and sludge

However, for a low flashpoint with a LOW implosion pressure, adiabatic compressive thermal heating degradation occurs to produce varnish from carbon insolubles such as coke, tars and resin.

stages_MD

Electrostatic Spark Discharge

ESD

What is Electrostatic Spark Discharge?

Electrostatic Spark Discharge is real and extremely common for turbine users!

Static electricity at a molecular level is generated when dry oil passes through tight clearances.

It is believed that the static electricity can build up to a point whereby it produces a spark.

There are three stages of ESD.

1. Static Electricity builds up to produce a spark – Temperatures exceed 10,000°C and the lubricant begins to degrade significantly.

2. Free radicals form – These contribute to the polymerisation of the lubricant

3. Uncontrolled polymerisation – Varnish and sludge produced (some may remain in solution or deposit on surfaces) which can also result in elevated fluid degradation and the presence of insoluble materials.