What Tools Can Be Used to Monitor Additive Depletion?

There are some basic analytical tools that can be used to measure the quantity of additives in oils. The spectroscopy methods are the FTIR (Fourier Transform Infrared) and ICP (Inductively Coupled Plasma). Another method is the RULER® test exclusively designed for antioxidants.

With FTIR and ICP methods, users obtain quantitative values for the elements present in the tested oil sample. These are usually reported in ppm and trended over time. Figure 2 shows an extract from a Turbine Sample report from Eurofins lab, where the levels of additives (and contaminants) are shown. When trending this, analysts should pay attention to the rate at which these additives decrease and whether an increase or decrease is noticed.

What Tools Can Be Used to Monitor Additive Depletion

Figure 2: Sample of Eurofins Turbine Oil Analysis Report showing the levels of additives

Another tool that can be used is the RULER® (Remaining Useful Life Evaluation Routine) test, which specifically quantifies the levels of antioxidants remaining in the oil. It trends the values, compares them against the baseline for that oil, and then determines the change as a percentage.

If the RULER value falls below 25%, the antioxidant levels have reached a critical level, and one may consider replacing the oil.

Figure 3 shows a RULER graph, which identifies the presence of different types of antioxidants (Amines) and antiwear additives (ZDDP), as well as oxidation products (Fluitec, 2022).

This is a comprehensive readout of the quantities of these additive types at the time of sampling. It is easy to get a quick snapshot of its trend over time and determine whether it is declining rapidly or reaching critical levels.

Figure 3: RULER Graph showing the presence of antioxidants

The key to using these analytical tools is to provide insight into what is happening inside the equipment, allowing us to determine whether any preventive action is needed.

By monitoring the quantities of these additives over time, we can easily establish whether oxidation is occurring, which can lead to varnish and overheating of the asset. We can also determine whether significant wear is occurring as the antiwear additives are depleted (confirmed by the presence of wear metals in the oil analysis). When monitoring your asset’s health, trending specific additive levels can also be very useful.

References

Eurofins. (2025, September 06). Annual Turbine Analysis. Retrieved from Eurofins Testoil: https://testoil.com/services/turbine-oil-analysis/annual-turbine-analysis/

Fluitec. (2022, September 29). Why is LSV Used for RULER Analysis? Retrieved from Fluitec: https://www.fluitec.com/2022/09/29/why-is-lsv-used-for-ruler-analysis/

Find out more in the full article, "Lubricant Additive Depletion as an Early Asset Health Signal" featured in Precision Lubrication Magazine by Sanya Mathura, CEO & Founder of Strategic Reliability Solutions Ltd.

Oil Properties

How Can Additives Deplete?

Additives can be depleted through different mechanisms. Some of these include:

Regular consumption through normal functioning of the lubricant
Antioxidant depletion during oxidation
Antiwear depletion due to high wear on the inside of the equipment
Additive depletion via a contaminant to produce a bleaching effect

As mentioned earlier, additives are sacrificial in nature. It is very normal to see additives deplete over time; if they are not depleting and increasing, this may be a cause for concern. This can mean that someone is topping up the oil frequently or perhaps topping up with an incorrect lubricant.

Since there are numerous oils on the market, the best way to monitor the depletion of your additives is to compare them against a new sample of that oil and use that as your baseline. Your lab will help you confirm when the additive limits are approaching the danger zones.

During oxidation, a free radical is formed under conditions such as heat, wear, metal catalysts, oxygen, or water. These free radicals are unstable, and antioxidants usually neutralize them.

In the process, antioxidant levels decrease. However, if the conditions still permit oxidation, more free radicals will be formed. This means that more antioxidants will be depleted as they neutralize the free radicals until they diminish and can no longer protect the base oil. This is when the free radicals begin to attack the base oil, and varnish can form.

Once the antioxidants are gone, the oil stops defending – and starts degrading.

If there are causes of high wear, such as the incorrect viscosity of the lubricant (too thin) or the machine finishing of the inner parts of a component not being done to the required standard, this can affect the levels of antiwear in the oil. Antiwear additives protect the metal surfaces inside the equipment. However, these are only activated when moderate stress exists within the equipment.

Typically, in these situations, the antiwear additive adheres to the metal surface and helps protect it by forming a layer. Once this layer is formed, the antiwear additive has officially left the oil, and this will be reflected in a decrease in its value in the oil analysis report.

The layer will not remain forever, and due to wear on the equipment, it can be worn off and replaced by a new layer, leading to further depletion of the antiwear additives until there are no more to form another layer or protect the metal surface.

Contamination can also cause some additives to become depleted. Contaminants can react with additives, causing them to form deposits that leave the oil. Therefore, their presence will not be detected by oil analysis.

Some common contaminants are water, fuel, coolant, and acids. These contaminants can also promote the formation of catalysts for degradation mechanisms such as oxidation. Dirt and solid particles can also promote additive depletion, especially when they act as catalysts.

Find out more in the full article, "Lubricant Additive Depletion as an Early Asset Health Signal" featured in Precision Lubrication Magazine by Sanya Mathura, CEO & Founder of Strategic Reliability Solutions Ltd.

Oil Properties

Why Do Additives Matter?

Oils are composed of base oils and additives. Typically, additives are sacrificial; they deplete first before the base oil is affected. As such, by trending their quantities over time, we can gain insight into a few of the conditions to which the oil is subjected.

By interpreting these conditions and patterns, we can correlate them with the health of the asset and plan accordingly for possible repairs or maintenance. In this article, we will do a deeper dive into ways these can be explored to add value to your asset management program.

Additives come in various ratios and chemical compositions, but when we talk about additives in oils, they really have three main functions. They can either;

Enhance the properties of the base oil, which already exist
Suppress the undesirable base oil properties or
Impart new properties to the base oil

Figure 1: Functions of additives and examples

On their own, they cannot affect anything, but when coupled with a base oil, they can impact an asset. Base oils also have specific properties, which, when combined with additives, allow assets to perform at their best.

The real performance comes from how the additives and base oil work together.

As shown in Figure 1, some additives that enhance properties include antioxidants, corrosion inhibitors, anti-foam agents, and demulsifying agents. Those responsible for suppressing undesirable properties can include pour-point depressants and viscosity improvers.

Finally, those responsible for imparting new properties include extreme-pressure additives, detergents, metal deactivators, and tackiness agents.

Here are some quick descriptions for a few of these additives, which will help you to gain an appreciation of their functions:

Antioxidants: these protect the oil from oxidation. They are very common in Turbine oils but can be found in many other oils. They are the first line of defense when oxidation begins and react with free radicals to neutralize them before they attack the base oil.

Corrosion inhibitors: adsorb onto the metal surfaces to help protect them. Comprised of sodium sulphonates, alkylbenzene sulphonates, or alkylphosphoric acid partial esters.

Anti-foam agents: reduce surface tension to break up foam formation. Typically, these are silicon-based, although silicone-free defoamers also exist.

Demulsifying agents: enable water and oil to separate. These were formerly composed of barium and calcium, but modern formulations use special polyethylene glycols.

Pour point depressant: alters oil crystallization, allowing the oil to form fewer crystals at lower temperatures.

Viscosity improvers: specifically designed to ensure that the viscosity of the lubricant can be more tolerant of changes in temperature and shear.

Extreme pressure additives: used under high stress to prevent the welding of moving parts. Usually comprised of a phosphorus compound.

Antiwear additives: designed to reduce wear under moderate stress. The most famous sulphur-phosphorus compound is ZDDP (Zinc Dialkyl dithiophosphate).

Detergents: keep oil soluble combustion products in suspension (especially for engine oils) and ensure they do not agglomerate. These usually contain metal additives such as Calcium and Magnesium.

Understanding the function and composition of these additives can help us to determine how they are performing in the oil. Since many of these are sacrificial, their values will decrease over time. As such, it is important to trend these values to determine whether they are remaining constant, increasing, decreasing, or decreasing at an accelerated rate.

Find out more in the full article, "Lubricant Additive Depletion as an Early Asset Health Signal" featured in Precision Lubrication Magazine by Sanya Mathura, CEO & Founder of Strategic Reliability Solutions Ltd.

Lubricant Degradation / Oil Properties / Reliability / Storage & Handling of Lubricants / Used Oil Analysis

Role of Condition Monitoring, Human & Organizational Factors in Oil Failures

Choosing the right oil for the system is just one part of the puzzle. How do we know the oil is performing when it’s in the system? This is where condition monitoring can work hand in hand to help ensure that the oil does not fail the asset.

If a proper oil analysis program does not exist, operators will not know whether the oil is properly lubricating the asset. They will also not be aware of whether the oil is breaking down too quickly and failing to protect the asset. Oil analysis can also alert operators to signs of wear in the asset, so they can fix them before they turn into functional failures.

An oil analysis program that lives in a drawer protects assets about as well as no program at all.

Role of Condition Monitoring, Human & Organizational Factors in Oil Failures

There is also the possibility that an oil analysis program exists but is not top of mind, or that its results are put in a drawer. This can also cause the asset to fail even though the correct oil is being used. Apart from the aforementioned factors, if operators are not warned of the impending failure of the oil, this can result in production losses, increased downtime, and, in some extreme cases, the complete loss of the asset if it has failed beyond repair.

Incorrect sampling is another area in which the actual condition of the asset is not reported. Even with the correct oil used, if a sample is collected from a dead leg or an area that is not truly representative of the conditions inside the component, its actual condition will not be known. With incorrect data about the component, the asset can be misdiagnosed or treated for symptoms that do not exist, which can lead to its detriment.

Human and Organizational Factors

Not all failures occur at the equipment level; human and organizational factors can also cause the asset to fail even when the correct oil is used. If humans aren’t properly trained in oil sampling techniques or storage and handling practices, these can affect the asset’s functionality. We often forget that, at the heart of it all, lies the human factor, which is partially governed by the organization’s systems.

Training needs are an organizational factor that is often overlooked when considering how an asset can fail. However, if operators have not been trained in condition monitoring techniques, they will not be able to read oil analysis reports or take appropriate actions to protect the asset. Training can help bridge some competency gaps that directly impact asset performance.

It doesn’t matter what oil is in the system if no one is trained to monitor it – or motivated to care.

Culture is another factor swept under the rug. If the culture doesn’t exist to look after the assets, it doesn’t matter what type of oil is placed in the system; the asset will fail eventually. The performance of the asset does not only rely on using the correct oil. By implementing a culture of Asset ownership, where operators look after the asset and are accountable for its performance, assets are optimized to provide the functionality they should. This is one way to ensure the right oil is used to enable the assets’ performance.

Another area of concern is the documentation of maintenance procedures. If maintenance procedures are not adequately documented, someone new to the operation may not be aware of the correct practice. This, coupled with a lack of training, can spell disaster for the equipment. In these cases, even though the right oil was selected, the wrong practice or lack thereof can fail the asset.

Turning the “Right oil” into the “Right Outcome.”

As explained in this article, improper practices can jeopardize the asset’s health, even when the right oil is used. However, if all the right things align, we can have an asset that lasts for its expected lifetime or beyond.

This starts with selecting the right oil based on the application, environmental conditions, and OEM recommendations. If we follow this up with good storage and handling practices, proper condition-monitoring programs, documentation, and training, we can look toward a longer-lasting asset. The right oil enables reliability – but only disciplined practices deliver it.

Find out more in the full article, "When 'Right oil, Wrong practice' still fails assets" featured in Precision Lubrication Magazine by Sanya Mathura, CEO & Founder of Strategic Reliability Solutions Ltd.

Lubricant Degradation / Oil Properties / Reliability / Storage & Handling of Lubricants / Used Oil Analysis

Common Modes of Failure for Lubricants

Regardless of the oil selected, common modes of failure can occur with every lubricant. These include: contamination, improper storage and handling practices, and environmental factors as shown in Figure 4.

Contamination can be defined as any foreign particle entering the system. This includes any gases, liquids, or solids. Especially when the lubricant system runs alongside the process side, process gases and liquids can leak into the oil. These contaminants can influence the oil’s degradation, leading to deposits or chemical reactions that break it down. Common process contaminants include ammonia or treated water.

The biggest threat to the right oil is often what gets added to it – whether it’s process contamination or the wrong oil during a top-up.

Another liquid that can contaminate oil is another oil. During top-ups, operators can add the wrong oil to the system, causing contamination and, depending on the oil, a possible shutdown. Adding motor oil to hydraulic oil can be catastrophic, as the additive packages work differently and the motor oil additives may counteract the hydraulic additives, removing them from the oil, leaving the asset open to wear and failure. Despite selecting the correct lubricant for your system, adding the wrong oil (mistakenly) will shorten its lifecycle and cause the asset to fail.

Bad storage and handling practices can also erode your oil, regardless of the oil you choose. Turbine and hydraulic oils are used in precise equipment. As such, they need to be clean and free of dirt or other contaminants. However, if oils are not stored correctly, contaminants can enter and contaminate the oil.

Simple techniques, such as transferring oil from larger storage containers (pails, drums, or totes) into smaller, more manageable containers (2-3 liters or less), can introduce contaminants into the oil if not done correctly. If oils are to be transferred to another storage container, the storage container must be clean. The transfer process should use clean hoses (not previously used for another lubricant) and be completed in a dust-free environment.

If you wouldn’t use a dirty needle for a blood transfusion, why would you use a dirty hose for an oil transfer?

The transfer of oils from one container to the next can be thought of as a blood transfusion. Would you use dirty needles or vials to transport the blood to be placed into another human? Similarly, oil can be likened to the equipment’s lifeblood and should be treated accordingly. Just as we observe sterile practices for blood transfusions, we should also observe similar types of practices for oil transfers.

Environmental and operational factors can also influence lubricant degradation. As stated earlier, all lubricants can degrade over time under harsh conditions. The lubricant formulation largely influences this, as does whether it was blended to withstand those conditions.

Oxidation can easily occur when temperatures increase, free radicals are present, or when wear metals are present. Thermal degradation occurs when the temperatures exceed 200°C. On the other hand, microdieseling occurs in the presence of entrained air, despite the lubricant used in the system, as shown in Figure 5.

Figure 5: Lubricant Degradation Processes

Any of these degradation mechanisms can occur regardless of the type of oil chosen. Hence, it is essential to remember that operational conditions and environmental factors can heavily influence oil degradation, even when the oil is appropriate for the system.

Find out more in the full article, "When 'Right oil, Wrong practice' still fails assets" featured in Precision Lubrication Magazine by Sanya Mathura, CEO & Founder of Strategic Reliability Solutions Ltd.

Oil Properties / Reliability

Spec Sheet vs Strategy for choosing the right oil

Sometimes we can spend hours poring over technical data sheets, comparing oil performances, and finally selecting the “right” oil which aligns with the needs of our equipment. Then, within 2 months, the oil degrades, our machines shut down, and we have a bunch of maintenance repairs lined up. What went wrong? We clearly had the “right” oil in the equipment; everything should have worked beautifully. This is where the awareness of lubrication and its practices becomes critical.

Having the correct oil is only one part of the puzzle. Being able to deliver that oil in its purest, cleanest form to the machine is often one of the other pieces that go missing. Another piece is selecting the right oil, not just based on the sales guy’s advice, but on the actual operating conditions of your machine. In this article, we dive a bit deeper into ways you can align the right oil with the proper practices, or avoid the wrong ones, to help extend the life of your asset.

Spec Sheet vs Strategy

For this example, we will consider a turbine oil selection. If a customer wants to change the oil in their turbine, then they may consider the following:

What are the OEM specifications that need to be met?
Is this oil available from the local supplier?
How does it compare to other oils on the market?
Does the cost justify the value? (or will the purchasing department want something cheaper?

For most of these questions, engineers or the person tasked with selecting the oil can readily find the answers in the oil’s technical data sheet and by talking to their sales representative. But if we dive a bit deeper, are we selecting the right oil for the operating and environmental conditions? Let’s examine the selection of a turbine oil for the Siemens SGT 200 Gas turbine that meets the Siemens TLV 9013 04 specification.

As seen in this document from Shell Lubricants, a few of their products meet that specification, namely Shell Turbo T, Turbo S2GX, Turbo S4X & Turbo S4GX.

Figure 1: Shell Turbo Family for the Siemens TLV 9013 04 Specification

On the other hand, Mobil provides some solutions as well, namely, Mobil DTE 732, 746, or DTE 832, 846

Figure 2: Mobil DTE 700 & 800 Series meeting the Siemens TLV 9013 04 Specification

Chevron also provides an option of Chevron GST as follows:

Figure 3: Chevron GST oil meeting the Siemens TLV 9013 04 specification

With so many options, how can one choose the “right” oil? They all meet the required Siemens specification, TLV 9013 04. This is where the data sheets, OEM manual, and knowledge of the equipment’s operating conditions play a crucial role.

As per the manual, there are preset conditions for temperatures and pressures, but if your actual system runs hotter (or production is being pushed a bit more), it is functioning outside the operating envelope.

The spec sheet tells you what the oil can do. Your operating conditions tell you what it must do.

Additionally, if your surroundings are harsh (close to the sea or in a corrosive environment, or in a non-ventilated area where heat can build up), these can place additional stress on the equipment. For these harsher conditions, a synthetic oil might be more appropriate than a mineral oil, albeit more expensive in terms of the initial investment.

The manual also specifies which tests/characteristics should be used to monitor the condition of the oil, namely: viscosity, particle count, water content, demulsibility, air release, foaming characteristics, RULER®, and MPC. Based on the performance of your current oil in the system, you can determine whether these values fluctuate toward the higher warning zones. This can also influence your decision about which oil to choose.

It’s not just about the right oil or one that aligns with OEM requirements. The selection should also be based on the environmental conditions of the oil and the equipment, and on whether the oil is suited to perform in these conditions. A mineral oil will not withstand the temperatures that a synthetic oil can for extended periods without degrading. Similarly, given the “right” conditions, synthetic oils can also degrade. By cross-examining your spec sheet, OEM manual, and actual conditions, you can determine the best-suited oil for your operations.

Find out more in the full article, "When 'Right oil, Wrong practice' still fails assets" featured in Precision Lubrication Magazine by Sanya Mathura, CEO & Founder of Strategic Reliability Solutions Ltd.

Oil Properties / Used Oil Analysis

Critical Condition Monitoring Tests for Compressor Oils

To ensure these oils remain healthy (and not contaminated or degraded), a few basic tests can be performed on all compressors, regardless of type (reciprocating, screw, refrigerant, etc.). These include:

Viscosity – this is key as some of the gases can easily affect the viscosity, which (if decreased) will not provide adequate separation for the interacting surfaces and cause wear. Generally, a ±10% limit is used (though OEMs may use different values).
Acid Number – if this begins increasing, then we have an accumulation of acids in the oil, which can be because of contamination. For most compressors, a 0.2 mg KOH/g increase is the warning limit, but for refrigeration compressors, the limit is tighter at +0.1 mg KOH/g. Always check with your OEM for these limits.
Water content – changes by OEM and refrigerant type, as the different gases will have varied tolerances.
Wear metals – these values will vary as per OEM, as well, since they are all designed with different types of metals. Users should look for trends or significant increases in these values to indicate wear.

Critical Condition Monitoring Tests for Compressor Oils

Some specialty tests for compressors include:

MPC (Membrane Patch Colorimetry) – this helps to measure if there is any potential for the oil to form varnish. Given the high temperatures these types of equipment endure and the potential for contamination, the oil is at risk of forming varnish. While limits will vary by OEM, some general guidelines to follow are 0-20 Normal, 20-30 Warning, >30 Action required
RULER® (Remaining Useful Life Evaluation Routine) – this quantifies the remaining level of antioxidants in the oil. When oxidation occurs, the antioxidants get depleted. As such, by monitoring antioxidant levels, one can easily determine whether oxidation is happening in the oil. The general rule of thumb is that if the level falls below 25%, there are not enough antioxidants to keep the oil healthy and prevent degradation.
Air Release (DIN ISO 9120) – measures the ability of the oil to allow air to escape and not keep the air in the oil. If air bubbles remain in the oil, this can be devastating, as it can lead to micropitting, cavitation, or increased oxidation. Users can trend the values; if they increase, it indicates that the air is taking longer to be released, which means it is staying in the oil and in the system longer.
Particle Count – this can identify if there are any contaminants in the system. These oils must be kept clean, and OEMs typically specify target cleanliness levels.

Compressors are critical equipment, and we must understand how they work and the lubricant specifications required. Monitoring their health can also help us avoid unnecessary downtime and keep our facilities running.

References

Mang, T., & Dresel, W. (2007). Lubricants and Lubrication. Weinheim: WILEY-VCH Verlag GmbH & Co. KGaA.
Totten, G. E. (2006). Handbook of Lubrication and Tribology – Volume 1 Application and Maintenance – Second Edition. Boca Raton: CRC Press.
Shell Lubricants. (2025, November 08). The Shell Corena range. Retrieved from Shell Lubricants Compressor Oils: https://www.shell.com/business-customers/lubricants-for-business/products/shell-corena-compressor-oils/_jcr_content/root/main/containersection-0/simple_1354779491/promo_1484925192/links/item0.stream/1759302155345/17be2a9a74057f321bb209128933f68f8b88ca70/s
ExxonMobil. (2025, November 08). Refrigeration Lubricant Selection for Industrial Systems. Retrieved from ExxonMobil Lubricants: https://www.mobil.com/lubricants/-/media/project/wep/mobil/mobil-row-us-1/new-pdf/refrigeration-lubricant-selection-for-industrial-systems.pdf
Chevron Lubricants. (2025, November 08). Optimizing compressor performance and equipment life through best lubrication practices Chevron. Retrieved from Chevron Lubricants: https://www.chevronlubricants.com/content/dam/external/industrial/en_us/sales-material/all-other/Whitepaper_CompressorOils.pdf

Find out more in the full article, "Compressor Oil, Types, Applications and Performance Drivers" featured in Precision Lubrication Magazine by Sanya Mathura, CEO & Founder of Strategic Reliability Solutions Ltd.

Oil Properties

Refrigeration Lubricants

For industrial refrigeration systems, there are a couple of essential pieces of information to consider before selecting the most suitable oil. The user must know the refrigerant in use, the evaporator type (dry or wet; carryover < 15%), the evaporator temperature, the compressor type, and the outlet temperature.

The refrigerant fluids are classified as per the ASHRAE classification (ANSI-ASHRAE Standard 34-2001):

R717 — Ammonia
R12 — Chlorofluorocarbon (CFC)
R22 — Hydrochlorofluorocarbon (HCFC)
R600a — Isobutane
R744 — Carbon dioxide (CO2)
R134a, R404a, R507 — Hydrofluorocarbons (HFC)

It should be noted that CFCs were banned under the Montreal Protocol (1989) due to their Ozone Depletion Potential, and HCFCs are being phased out due to their Global Warming Potential.

Chevron provides some general guidelines for selecting the appropriate refrigerant, as shown in the table below.5

(But you should always follow the guidelines of your OEM when selecting the appropriate lubricant.)

Table 1: Refrigerants and their associated lubricant technologies

ExxonMobil classifies its refrigeration lubricants based on refrigerant type, evaporator temperature, and compressor type (Piston, Screw, or Centrifugal). This is very helpful when determining the best-suited lubricant for your refrigerant compressor.

Check out the pdf here.

Find out more in the full article, "Compressor Oil, Types, Applications and Performance Drivers" featured in Precision Lubrication Magazine by Sanya Mathura, CEO & Founder of Strategic Reliability Solutions Ltd.

Oil Properties

Industry Standards for Compressor Oils

Some other classifications which users may see when dealing with compressor oils (even though some of these standards may be dated) include:

ISO 6743-3, which uses the following acronyms for associated compressors:

DAA, DAB, DAG to DAJ: Air compressors
DVA to DVF: Vacuum pumps
DGA to DGE: Gas compressors
DRA to DRG: Refrigeration compressors

In this standard, the “D” family includes detailed classifications of lubricants used in air, gas, and refrigeration compressors. The second letter usually indicates the type of compressor, and the third letter indicates the application severity or type, especially for gas or refrigeration compressors.

For instance;

DAJ represents:

D -> Compressor Lubricant

A -> Air compressor

J-> Lubricant drain cycles of >4000 hours

DVB represents:

D-> Compressor Lubricant

V->Vacuum pumps, Positive Displacement Vacuum pumps with oil lubricated compression chambers, Reciprocating and rotary drip feed, Rotary oil-flooded (vane and screw)

B-> Low vacuum for aggressive gas (10² to10^-1kPa or 10³ to 1 mbar)

DGD represents:

D-> Compressor Lubricant

G-> Positive displacement reciprocating and rotary compressors for all gases, Compressors for refrigeration circuits or heat pump circuits, together with air compressors, are excluded.

D-> Gases that react chemically with mineral oil, usually synthetic fluids, HCI, CI2, O2, and oxygen-enriched air at all pressures. CO₂ at pressures above 10³ kPa (10 bar) with O2- and oxygen-enriched air: mineral oils are prohibited, and very few synthetic fluids are compatible.

DRB represents:

D-> Compressor Lubricant

R-> Compressors, refrigeration systems

B-> Ammonia (NH3), Miscible, Polyalkylene glycol, Commercial and industrial refrigeration, For direct expansion evaporators; PAGs for open compressors and factory-built units.

Another standard which is also used in this industry is DIN 51506, which defines:

VB, VC: Uninhibited mineral oils (no oxidation inhibitors)
VBL: Mineral oil-based engine oil (additives that protect from corrosion and oxidation and air compressor temperatures up to 140°C)
VCL: Mineral oil-based engine oil (additives that protect from corrosion and oxidation and air compressor temperatures up to 160°C)
VDL: Inhibited oils with increased aging resistance (additives that protect from corrosion and oxidation and air compressor temperatures up to 220°C, recommended for compressors with 2-stage compression)

One more standard is DIN 52503, which has these classifications:

KAA: Not miscible with ammonia
KAB: Miscible with ammonia
KB: For carbon dioxide (CO2)
KC: For partly and fully halogenated fluorinated and chlorinated hydrocarbons (CFC, HCFC)
KD: For partly and fully fluorinated hydrocarbons (HFC, FC)
KE: For hydrocarbons (e.g., propane, isobutane)

These standards are referenced when discussing certain compressor oils, and their definitions are helpful for navigating acronyms.

Find out more in the full article, "Compressor Oil, Types, Applications and Performance Drivers" featured in Precision Lubrication Magazine by Sanya Mathura, CEO & Founder of Strategic Reliability Solutions Ltd.

Oil Properties

Types of Compressors and Oils

Compressors are integral to many of our operations. They are used to compress gas, increasing its pressure, and to power tools. They can also be used as vacuum pumps or blowers, but each application is different. As such, they require various types of lubrication, particularly for applications that use specific refrigerants and come into contact with the lubricant.

In all these applications, the functions of the oil remain largely the same: it must lubricate the surfaces, prevent wear and corrosion, maintain the required viscosity, and provide proper sealing.

In this article, we will dive into the various types of compressor oils and explain why they are suited to these applications. We will also discuss monitoring the health of these oils and the tests that should be performed to ensure your compressor oils remain healthy.

Types of Compressors

Essentially, there are two main types of compressors: Displacement and Dynamic. For displacement compressors, gas is drawn into a chamber, compressed, and expelled by a reciprocating piston. On the other hand, for dynamic compressors, turbine wheels accelerate a medium, which is then abruptly accelerated.¹

Positive displacement compressors include Reciprocating and Rotating compressors. These can be further subdivided as shown in Figure 1. For Dynamic (Turbo) compressors, these are further subdivided into Centrifugal, Axial, and Mixed types (also shown in Figure 1).

Figure 1: Types of compressors

Depending on the type of compressor, the required lubricant will vary. For example, positive-displacement compressors use rolling or sliding motion and include bearing and sealing components within the compression chamber. On the other hand, dynamic compressors use hydrodynamic journal and thrust bearings, or rolling-element bearings, to support the main shaft, which is isolated from the compression chamber.

Working pressures, temperatures, and the type of gas being compressed also play a significant role in determining the appropriate lubricant.²

As with most applications, there can be a dry-sump or a wet-sump. Wet sumps are typically seen in reciprocating and rotary screw compressors. In a wet sump, the gas usually contacts the oil, lowering its viscosity. This is where it is essential to note the gas’s solubility in the system oil. Natural gas and other hydrocarbons are more soluble in mineral oils and PAOs than in PAGs and diesters. Thus, PAGs may be preferred in some cases to avoid lubricant failure.

Compressor Oils

Most of the major global lubricant OEMs have classified their oils based on:

Rotary vane and screw air compressor oils
Reciprocating (piston) air compressor oils
Refrigeration compressor oils

As seen below in Figure 2, Shell Lubricants³ has a line of lubricants, particularly for air compressors, which are further classified into mineral oils, PAOs, and PAGs for Rotary vane and screw air compressors or Reciprocating (piston) air compressors.

Figure 2: Shell Lubricants for Air Compressors

In reciprocating air compressors, cylinder design dictates the lubrication type, as this is the most severe application. Compressing the gas usually results in high temperatures, which can easily lead to oxidation. The compressed gas must be free of contaminants, as contaminants can accelerate oxidation. Typically, for reciprocating air compressors, mineral oils or PAO- or di-ester-based lubricants in the ISO VG 68 to 150 range are preferred.

Rotary vane compressors can experience pressure extremes as the vanes slide to compress the gas, and oil is continuously injected into the compressor chambers. Typically, ISO VG 68-150 oils are used in this application.

Figure 3: Reciprocating Piston vs Screw Compressor Lubricant Needs

For screw compressors, the oil must perform several functions, including lubricating the meshing rotors and the plain and roller bearings that form part of the geared coupling. ISO VG 46 mineral oils are usually used in these compressors, but the viscosity can be increased to ISO VG 68 or to synthetic PAO or PAG lubricants at higher ambient temperatures. Similarly, Group III base oils of these viscosities can be used in this area. Most screw compressor oils contain mild EP/AW performance additives and require an FZG failure load≥10.

Ideally, reciprocating piston compressors will use higher viscosities (ISO VG 100-150) with extremely low carbon residue and no or mild EP/AW additives. Conversely, screw compressors will use lower viscosities (ISO VG 46 or 68) with excellent oxidation stability and mild/high AW/EP additives1, as shown in Figure 3.

Find out more in the full article, "Compressor Oil, Types, Applications and Performance Drivers" featured in Precision Lubrication Magazine by Sanya Mathura, CEO & Founder of Strategic Reliability Solutions Ltd.

Tagged: strategic reliability solutions

References

Human and Organizational Factors

Turning the “Right oil” into the “Right Outcome.”

Spec Sheet vs Strategy

Types of Compressors

Compressor Oils